| Country | Capital |
|---|---|
| Algeria | Algiers |
| Angola | Luanda |
| Benin | Porto Novo |
| Botswana | Gaborone |
| Burkina Faso | Ouagadougou |
| Burundi | Bujumbura |
| Cameroon | Yaoundé |
| Cape Verde | Praia |
| Central African Republic | Bangui |
| Chad | N'Djamena |
| Comoros | Moroni |
| Democratic Republic of Congo | Kinshasa |
| Djibouti | Djibouti |
| Egypt | Cairo |
| Equatorial Guinea | Malabo |
| Eritrea | Asmara |
| Eswatini | Mbabane |
| Ethiopia | Addis Ababa |
| Gabon | Libreville |
| Gambia | Banjul |
| Ghana | Accra |
| Guinea | Conakry |
| Guinea-Bissau | Bissau |
| Ivory Coast | Yamoussoukro |
| Kenya | Nairobi |
| Lesotho | Maseru |
| Liberia | Monrovia |
| Libya | Tripoli |
| Madagascar | Antananarivo |
| Malawi | Lilongwe |
| Mali | Bamako |
| Mauritania | Nouakchott |
| Mauritius | Port Louis |
| Morocco | Rabat |
| Mozambique | Maputo |
| Namibia | Windhoek |
| Niger | Niamey |
| Nigeria | Abuja |
| Republic of the Congo | Brazzaville |
| Rwanda | Kigali |
| São Tomé and Príncipe | São Tomé |
| Senegal | Dakar |
| Seychelles | Victoria |
| Sierra Leone | Freetown |
| Somalia | Mogadishu |
| South Africa | Pretoria |
| South Sudan | Juba |
| Sudan | Khartoum |
| Tanzania | Dodoma |
| Togo | Lomé |
| Tunisia | Tunis |
| Uganda | Kampala |
| Zambia | Lusaka |
| Zimbabwe | Harare |
Source (2025) : United Nations (list of UN member states and permanent observers)